• 专利附录
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    • 专利摘要:
    The invention relates to an aerosol device which contains a composition comprising: (i) one or more water-insoluble calcium salts, (ii) one or more fixing polymers, (iii) one or more surfactants, (iv) water, and (v) less than 20% by weight, based on the total weight of the composition, of one or more propellants. It also relates to a method of shaping the hair and / or maintaining the hairstyle, using the aerosol device of the invention.
    公开号:FR3022770A1
    申请号:FR1456128
    申请日:2014-06-30
    公开日:2016-01-01
    发明作者:Jonathan Gawtrey；Dorothee Pasquet
    申请人:LOreal SA；
    IPC主号:
    专利说明:

    [0001] The present invention relates to an aerosol device comprising a composition based on at least one calcium salt insoluble in water, of at least one fixing polymer and at least one surfactant in water, and its use for the treatment of hair, especially for shaping the hair and / or maintaining the hairstyle. Hair products for shaping and / or maintaining the hairstyle most common in the cosmetics market are spray compositions, such as lacquers, sprays and foams. They consist essentially of an aqueous or hydroalcoholic solution and one or more materials, generally polymeric resins, also called fixing components, whose function is to form welds between the hair, mixed with various cosmetic adjuvants.
    [0002] These products make it possible to secure and hold the hairstyle in time, but they tend to freeze the hair, giving the impression of having a helmet, called helmet effect. This criterion is often perceived negatively by consumers. During the day, if the user passes the hands in the hair, the fixation provided by these hair products is reduced. To date, the polymers conventionally used do not make it possible to restore the shape of the hairstyle if it has been disturbed. The volume of the hairstyle also tends to decrease sharply during the day, especially for fine hair. There is therefore a need to provide products that make it possible to fix and maintain the hairstyle in a more natural way, without freezing the hair and which make it possible to restore the shape of the hairstyle. The Applicant has surprisingly and advantageously found that the combination of a water-insoluble calcium salt with a fixing polymer and a surfactant in water, the whole being conditioned in an aerosol device in the presence of less than 20% by weight of propellant, relative to the total weight of the combination and of the propellant, made it possible to obtain a foam which brings to the hairstyle volume, of texturisation (that is to say a contribution of matter, of density, with a feeling of a hair thicker), of the mass (that is to say an impression of a greater quantity of hair) and a maintenance without fixed effect. The subject of the invention is therefore an aerosol device which contains a composition, preferably a cosmetic composition, comprising: (i) one or more calcium salts which are insoluble in water, (ii) one or more fixing polymers, (iii) one or more several surfactants, (iv) water, preferably in an amount greater than 5% by weight relative to the total weight of the composition, (v) less than 20% by weight, relative to the total weight of the composition, one or more propellants. This particular combination allows shaping and / or maintaining the hairstyle by texturing without freezing. It also allows a recovery of the shape of the hairstyle even after it has been deliberately modified or not. The hairstyle can also be remodeled during the day, without additional product application. This association also has a particularly remarkable effect on the volume of the hairstyle.
    [0003] A significant decrease in the perceived white effect on hair with solid particle products is also obtained. The application of the composition according to the invention can be done on both wet and dry hair.
    [0004] The present invention also relates to a method of treatment, and in particular of shaping the hair and / or maintaining the hairstyle, comprising spraying the hair with the composition according to the invention.
    [0005] It also relates to the use of the sprayed composition from this aerosol device, for shaping the hair and / or maintaining the hairstyle, and in particular to give volume to the hairstyle. Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and the example which follows. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field, especially in the expressions "between" and "from ... to". Moreover, the expression "at least one" used in the present description is equivalent to the expression "one or more". According to the invention, the aerosol device contains a composition comprising: (i) one or more calcium salts insoluble in water, preferably having an average particle size ranging from 2 μm to 50 μm, one or more fixing polymers, one or more surfactants, water, preferably in an amount greater than 5% by weight relative to the total weight of the composition, (v) less than 20% by weight, relative to the total weight of the composition, of one or more propellants. For the purpose of the present invention, the term "insoluble in water" means a compound whose solubility at spontaneous pH in water at 25 ° C. and at atmospheric pressure is less than 0.1%. The calcium salt can be mineral or organic. It is preferably mineral.
    [0006] As calcium salt insoluble in water, there may be mentioned calcium carbonate or calcium stearate. The calcium salt is preferably calcium carbonate. The water-insoluble calcium salt is in particular in the form of a powder comprising particles which preferably have an average diameter of 2 to 50 microns, preferably 5 to 40 microns, better still order of 30 i.tm. The calcium salt (s) is (are) present in an amount ranging preferably from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, and even more preferably from 0.7 to 6% by weight relative to the total weight of the composition. As indicated above, the composition according to the invention comprises one or more fixing polymers. The term "fixing polymer", any polymer capable of conferring a shape to a hair or to maintain a hair in a given form. The fixing polymer (s) used in the aerosol device according to the invention are chosen from anionic, cationic, amphoteric and nonionic fixing polymers, and mixtures thereof.
    [0007] As anionic fixing polymers, mention may be made of polymers containing groups derived from carboxylic, sulfonic or phosphoric acids and having a number-average molecular mass of between 500 and 5,000,000. The carboxylic groups are provided by monoacid monomers or unsaturated dicarboxylic acids such as those having the formula: R 1 / (A), -COOH (I) C = CR (R 3) wherein n is an integer from 0 to 10, A denotes a methylene group, optionally connected to the carbon atom of the unsaturated group or the neighboring methylene group when n is greater than 1, via a heteroatom such as oxygen or sulfur, R1 denotes a hydrogen atom, a phenyl or benzyl group, R2 denotes a hydrogen atom, an alkyl group comprising from 1 to 4 carbon atoms or carboxyl, R3 denotes a hydrogen atom, an alkyl group containing from 1 to 4 carbon atoms, a group -CH 2 -COOH, phenyl or benzyl. In the formula (I) above, the alkyl group having from 1 to 4 carbon atoms may in particular designate the methyl and ethyl groups. The anionic fixing polymers containing carboxylic or sulphonic groups are: A) copolymers of acrylic or methacrylic acid or their salts, of which the copolymers of acrylic acid and of acrylamide and the copolymers of methacrylic acid / acrylic acid / ethyl acrylate methyl methacrylate, in particular AMERHOLD DR 25 marketed by AMERCHOL, and the sodium salts of polyhydroxycarboxylic acids. Mention may also be made of methacrylic acid / ethyl acrylate copolymers, especially in aqueous dispersion, such as the Luviflex Softs and Luvimerars sold by the company BASF. B) copolymers of acrylic or methacrylic acids with a monoethylenic monomer such as ethylene, styrene, vinyl esters, esters of acrylic or methacrylic acid, optionally grafted onto a polyalkylene glycol such as polyethylene glycol, and optionally crosslinked. Such polymers are described in particular in French Patent 1,222,944 and German Application No. 2,330,956, copolymers of this type comprising in their chain an acrylamide unit optionally N-alkylated and / or hydroxyalkylated as described in particular in US Pat. patent applications 75370 and 75371. Also include copolymers of acrylic acid and C1-C4 alkyl methacrylate.
    [0008] As another anionic fixing polymer of this family, mention may also be made of the branched-chain anionic polymer butyl acrylate / acrylic acid / methacrylic acid sold under the name Fixate G-100 L by the company LUBRIZOL (INCI name AMP-ACRYLATES / ALLYL METHACRYLATE COPOLYMER ). C) copolymers derived from crotonic acid, such as those comprising in their chain vinyl acetate or propionate units, and optionally other monomers such as the allyl or methallyl ester, vinyl ether or vinyl ester of a saturated carboxylic acid, linear or branched, long hydrocarbon chain, such as those comprising at least 5 carbon atoms, these polymers may optionally be grafted and crosslinked, or a vinyl ester, allyl or methallylique a carboxylic acid α or β-cyclic. Such polymers are described, inter alia, in French patents Nos. 1,222,944, 1,580,545, 2,265,782, 2,265,781, 1,564,110 and 2,439,798. Commercial products in this class are resins 28-29. Nos. 30, 26-13-14 and 28-13-10 sold by the company National Starch, Crotonic acid terpolymers Crotonic acid / vinyl acetate / tertiobutyl terpolymers may also be mentioned as copolymers derived from crotonic acid. vinyl benzoate and in particular MEXOMERE PW supplied by the company CHIMEX. D) Polymers derived from maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters; these polymers can be esterified. Such polymers are described in particular in US Pat. Nos. 2,047,398, 2,723,248, 2,102,113 and GB 839,805, and in particular those sold under the names GANTREZ® AN or ES by the company ISP. Polymers also falling into this class are copolymers of maleic anhydride, citraconic anhydride, itaconic anhydride and an allylic or methallyl ester optionally containing an acrylamide, methacrylamide, an α-olefin, acrylic or methacrylic ester, acrylic or methacrylic acid group. or vinylpyrrolidone in their chain, the anhydride functions are monoesterified or monoamidified. These polymers are for example described in French patents 2,350,384 and 2,357,241 of the applicant. E) Polyacrylamides having carboxylate groups. F) polymers comprising sulfonic groups. These polymers may be polymers comprising vinylsulphonic, styrene-sulphonic, naphthalenesulphonic, acrylamido-alkylsulphonic, sulfoisophthalate units. These polymers may be chosen in particular from: polyvinylsulfonic acid salts having a molecular weight of between about 1,000 and 100,000, as well as copolymers with an unsaturated comonomer such as acrylic or methacrylic acids, and their esters, as well as acrylamide or its derivatives, vinyl ethers and vinylpyrrolidone; polystyrenesulfonic acid salts, sodium salts having a molecular weight of about 500,000 and about 100,000.
    [0009] These compounds are described in patent FR 2198719; polyacrylamidesulfonic acid salts such as those mentioned in US Pat. No. 4,128,631; G) grafted anionic silicone polymers; The grafted silicone polymers used are preferably chosen from polymers having a non-silicone organic skeleton grafted with monomers containing a polysiloxane, polymers with a polysiloxane backbone grafted with non-silicone organic monomers, and mixtures thereof. H) Anionic polyurethanes, which may comprise silicone grafts and silicones with hydrocarbon grafts. As examples of fixing polyurethane, there may be mentioned in particular the copolymer dimethylolpropionic acid / isophoronediisocyanate / neopentylglycol / polyesterdiol s (also known under the name of polyurethane-1, INCI designation) sold under the trademark Luviset® PUR by the company BASF, the dimethylolpropionic acid copolymer / sophorone-diisocyanate / neopentylglycol / polyesterdiols / silicone diamine (also known under the name of polyurethane-6, INCI designation) sold under the trademark Luviset® Si PUR A by the company BASF. As another anionic polyurethane, it is also possible to use AVALURE UR 450. It is also possible to use polymers containing sulfoisophthalate groups, such as the AQ55 and AQ48 polymers marketed by EASTMAN. According to the invention, the anionic fixing polymers are preferably chosen from acrylic acid copolymers such as the acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymer sold under the name ULTRAHOLD STRONG® by BASF, the acidic copolymers methacrylic / ethyl acrylate, especially in aqueous dispersion, such as LUVIFLEX SOFT and LUVIMER MAE marketed by BASF, copolymers derived from crotonic acid such as terpolymers vinyl acetate / vinyl tert-butylbenzoate / crotonic acid and the crotonic acid / vinyl acetate / vinyl neododecanoate terpolymers sold under the name Resin 28-29-30 by the company National Starch, polymers derived from maleic, fumaric or itaconic acids or anhydrides with vinyl esters and ethers vinyl, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters such as copoly monoesterified methyl vinyl ether / monoesterified maleic anhydride sold under the name Gantrez® ES 425 by the company ISP, the LUVISET SI PUR, the MEXOMERE PW, the anionic polyurethanes elastomers or not, the polymers with sulfoisophthalate groups, the anionic fixing polymers of the family B) and even more particularly, the branched anionic block polymer, butyl acrylate / acrylic acid / methacrylic acid sold under the name Fixate G-100 L by the company LUBRIZOL (INCI name AMP-ACRYLATES / ALLYL METHACRYLATE COPOLYMER) is preferably used.
    [0010] The cationic fixing polymers that can be used according to the present invention are preferably chosen from polymers containing primary, secondary, tertiary and / or quaternary amine groups forming part of the polymer chain or directly connected thereto, and having a molecular weight between 500 and about 5,000,000 and preferably between 1,000 and 3,000,000. Among these polymers, there may be mentioned more particularly the following cationic polymers: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and having at least one of the following units: R3i R3i R3i CH-C- -CH-C- or 2 2 C = O CO = CO = I (A) (B) NH AAA (C) R4 N R6 X R4 N Wherein R3 is hydrogen or CH3; A is a linear or branched alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl group; R1 and R2, identical or different, each represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; X denotes a methosulphate anion or a halide such as chloride or bromide.
    [0011] The copolymers of family (1) also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones-acrylamides, acrylamides and methacrylamides substituted on the nitrogen by C 1 -C 4 alkyl groups. groups derived from acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these copolymers of the family (1), mention may be made of: the copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC® by the HERCULES company, the copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride described for example in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, such as the product sold under the name Reten by the company Hercules, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers, whether or not quaternized, such as the products sold under the name "GAFQUAT®" by ISP, for example " GAFQUAT® 734 "or" GAFQUAT® 755 "or products referred to as" COPOLYMER® 845, 958 and 937 ". These polymers are described in detail in French Pat. Nos. 2,077,143 and 2,393,573, the polymers with a fatty chain and with a vinylpyrrolidone unit, such as the products sold under the name Stylèze W20 and Stylèze W10 by ISP, and terpolymers. dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone, such as the product sold under the name GAFFIX VC 713 by the company ISP, and the quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymers, such as the products sold under the name "GAFQUAT® HS 100" by the company ISP company. (2) cationic, preferably quaternary ammonium guar gums such as those described in US Pat. Nos. 3,589,578 and 4,031,307 such as guar gums containing cationic trialkylammonium groups. Such products are marketed in particular under the trade names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 by MEYHALL. (3) quaternary copolymers of vinylpyrrolidone and vinylimidazole; (4) chitosans or their salts; the salts that can be used are, in particular, the acetate, lactate, glutamate, gluconate or pyrrolidonecarboxylate of chitosan.
    [0012] Among these compounds, mention may be made of chitosan having a degree of deacetylation of 90.5% by weight sold under the name KYTAN BRUT STANDARD by ABER TECHNOLOGIES, the pyrrolidone carboxylate of chitosan sold under the name KYTAMER® PC by the company Amerchol. (5) cationic cellulose derivatives such as copolymers of cellulose or of cellulose derivatives grafted with a water-soluble monomer comprising a quaternary ammonium, and described in particular in US Pat. No. 4,131,576, such as hydroxyalkyl celluloses, such as hydroxymethyl- hydroxyethyl or hydroxypropyl cellulose grafted in particular with a salt of methacryloyloxyethyltrimethylammonium, methacrylamidopropyl trimethylammonium, dimethyl-diallylammonium. The marketed products corresponding to this definition are more particularly the products sold under the name "CELQUAT L 200" and "CELQUAT H 100" by the company National Starch, or "CELQUAT LOR" by the company Akzo Nobel, and correspond to the polyquaternium. 4. (6) polymers comprising in their structure: (a) one or more units corresponding to the following formula (A1): -CH 2 CH (NH 2) - (A1) (b) optionally one or more units corresponding to formula (B1) following: -CH 2 CH (NHCOH) - (B1) In other words, these polymers may be chosen in particular from homo- or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide. Mention may be made, for example, of vinylamine / vinylformamide copolymers such as the product provided by BASF under the trade name Luviquat 9030 of the INCI vinylamine / vinylformamide copolymer denomimation. Preferred cationic fixing polymers are chosen from those of the family (5) or of the family (6). More particularly, the cationic fixing polymer may be chosen from the hydroxyethylcellulose / diallyl dimethyl ammonium chloride copolymer INCI name polyquaternium-4, and the vinylamine / vinylformamide copolymer, INCI vinylamine / vinylformamide copolymer denomimation.
    [0013] The amphoteric fixing polymers that may be used in accordance with the invention may be chosen from polymers comprising units B and C statistically distributed in the polymer chain, where B denotes a unit derived from a monomer comprising at least one basic nitrogen atom and C denotes a unit derived from an acidic monomer having one or more carboxylic or sulphonic groups or else B and C may denote groups derived from zwitterionic monomers of carboxybetaines or of sulphobetaines; B and C may also designate a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic or sulphonic group connected via a hydrocarbon group, or Well B and C are part of a chain of an ethylene-dicarboxylic-containing polymer having one of the carboxylic groups reacted with a polyamine having one or more primary or secondary amine groups. The amphoteric fixing polymers as defined above, which are more particularly preferred, are chosen from the following polymers: 1) the polymers resulting from the copolymerization of a monomer derived from a vinyl compound carrying a carboxylic group such as that more particularly acrylic acid, methacrylic acid, maleic acid, alpha-chloro acrylic acid, and a basic monomer derived from a substituted vinyl compound containing at least one basic atom such as, more particularly, dialkylaminoalkylmethacrylate and acrylate, dialkylaminoalkylmethacrylamide and acrylamide. Such compounds are described in U.S. Patent No. 3,836,537.
    [0014] The vinyl compound may also be a dialkyldiallylammonium salt such as diethyldiallylammonium chloride. 2) polymers comprising units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen with an alkyl group; b) with at least one acidic comonomer containing one or more reactive carboxylic groups and c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituent esters of acrylic and methacrylic acids, and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate. The N-substituted acrylamides or methacrylamides which are more particularly preferred according to the invention are the groups in which the alkyl groups contain from 2 to 12 carbon atoms and more particularly N-ethylacrylamide, N-tert-butylacrylamide, N-tert-octylacrylamide, N octyl. N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides. The acidic comonomers are chosen more particularly from acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids as well as alkyl monoesters having 1 to 4 carbon atoms of maleic or fumaric acids or anhydrides. Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl, N-tert-butylaminoethyl methacrylates. The copolymers whose CTFA (4th Ed., 1991) name is octylacrylamide / acrylates / butylaminoethylmethacrylate copolymer, such as the products sold under the name AMPHOMER® or LOVOCRYL® 47 by the company National Starch, are particularly used. 3) partially or completely crosslinked polyamino amides derived from polyamino amides of the general formula: ## STR2 ## in which R 4 represents a divalent group derived from a saturated dicarboxylic acid, an aliphatic mono or dicarboxylic acid with an ethylenic double bond; , an ester of an alcohol having 1 to 6 carbon atoms of these acids or a group deriving from the addition of any of said acids with a primary amine bis or bis secondary derivative, and Z denotes a group of a bis-primary, mono or bis-secondary polyalkylene polyamine and preferably represents: a) in the proportions of 60 to 100 mol%, the group NH-E (CH 2) x -NH where x = 2 and p = 2 or 3, or x = 3 and p = 2 this group derived from diethylene triamine, triethylene tetraamine or dipropylene triamine; b) in the proportions of 0 to 40 mol%, the group (III) above, in which x = 2 and p = 1 and which is derived from ethylenediamine, or the group derived from piperazine / -N N-c) in the proportions of 0 to 20 mol%, the -NH- (CH 2) 6 -NH- group derived from hexamethylenediamine, these polyaminoamines being crosslinked by addition of a bifunctional crosslinking agent chosen from epihalohydrins, diepoxides, dianhydrides, bis unsaturated derivatives, by means of 0.025 to 0.35 mole of crosslinking agent per amine group of the polyaminoamide and alkyls by the action of acrylic acid, chloroacetic acid or an alkane-sultone or of their salts. The saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms such as adipic acid, 2,2,4-trimethyladipic acid and 2,4,4-trimethyladipic acid, terephthalic acid, ethylenically double-bonded acids such as for example, acrylic, methacrylic, itaconic acids. The alkanesultones used in the alkylation are preferably propane or butane sultone, the salts of the alkylating agents are preferably the sodium or potassium salts. 4) polymers comprising zwitterionic units of formula: ## STR3 ## in which R 5 denotes a polymerizable unsaturated group such as an acrylate and methacrylate group; , acrylamide or methacrylamide, y and z each represent an integer of 1 to 3, R6 and R7 represent a hydrogen atom, a methyl, ethyl or propyl group, R8 and R9 represent a hydrogen atom or an alkyl group of such that the sum of the carbon atoms in R10 and R11 does not exceed 10. The polymers comprising such units may also comprise units derived from non-zwitterionic monomers such as dimethyl- or diethylaminoethyl acrylate or methacrylate, or alkyl acrylates or methacrylates, acrylamides or methacrylamides, or vinyl acetate. 5) polymers derived from chitosan having monomeric units corresponding to the following formulas: ## STR2 ## ## STR2 ## ## STR2 ## Embedded image wherein the unit (V) is present in proportions of between 0 and 30%, and the unit (VI) in proportions of between 5 and 50%. and the unit (VII) in proportions of between 30 and 90%, it being understood that in this unit F, R10 represents a group of formula: ## STR2 ## in which if q = 0, R11, R12 and R13, which are identical or different, each represent a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine residue or a dialkylamine residue optionally interrupted by one or more nitrogen atoms and / or optionally substituted by one or more amine, hydroxyl, carboxyl, alkylthio or sulphonic groups, an alkylthio residue whose alkyl group carries an amino residue, one at least R17, R18 and R19 groups being in this case a hydrogen atom; or if q = 1, R 11, R 12 and R 13 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids. 6) The polymers derived from the N-carboxyalkylation of chitosan. 7) The polymers of units corresponding to the general formula (IX) described, for example, in French Patent 1,400,366: R14 (CH-CH2) CH CH COOH NR NR NR17 R16 (IX) in which R14 represents a hydrogen atom, a group CH 3 0, CH 3 CH 2 O, phenyl, R 15 denotes hydrogen or a C 1-4 alkyl group such as methyl and ethyl, R 16 denotes hydrogen or a C 1-4 alkyl group such as methyl and ethyl, R 17 denotes a C1-C4 alkyl group such as methyl and ethyl or a group corresponding to the formula: -R18-N (R16) 2, R18 representing a group -CH2-CH2-, -CH2-CH2-CH2-, -CH2-CH (CH3 ) -, R16 having the meanings mentioned above, as well as the higher homologues of these groups and containing up to 6 carbon atoms. 8) Amphoteric polymers of the -DXDX- type chosen from: a) the polymers obtained by the action of chloroacetic acid or sodium chloroacetate on the compounds comprising at least one unit of formula: -DXDXD- (X) where D denotes a group -N and X denotes the symbol E or E ', E or E', which may be identical or different, denote a divalent group which is a straight or branched chain alkylene group having up to 7 carbon atoms in the chain main unsubstituted or substituted by hydroxyl groups, and may further include oxygen, nitrogen, sulfur, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulphoxide, sulphone, sulphonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide groups, alcohol, ester and / or urethane. b) polymers of formula: -D-X-D-X- (XI) where D denotes a group / -N N- and X denotes the symbol E or E 'and at least once E'; E having the meaning indicated above and E 'is a divalent group which is a straight or branched chain alkylene group having up to 7 carbon atoms in the main chain, substituted or unsubstituted by one or more hydroxyl groups and having a or a plurality of nitrogen atoms, the nitrogen atom being substituted by an optionally interrupted alkyl chain by an oxygen atom and necessarily comprising one or more carboxyl functions or one or more hydroxyl functions and betaineized by reaction with chloroacetic acid or chloroacetate of soda. 9) The alkyl (C 1 -C 5) vinyl ether / maleic anhydride copolymers partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semi-esterification with an N, N-dialkanolamine These copolymers may also comprise other vinylic comonomers such as vinylcaprolactam.
    [0015] According to a preferred embodiment of the invention, the amphoteric fixing polymers that may be used in the aerosol device according to the invention may be chosen from branched block copolymers, comprising: (a) nonionic units derived from at least one monomer selected from C1-C20 alkyl (meth) acrylates, N-mono- (C2-C12) alkyls (meth) acrylamides and N, N-di (C2-C12) alkyls - ( meth) acrylamide, (b) anionic units derived from at least one monomer selected from acrylic acid and methacrylic acid, and (c) polyfunctional units derived from at least one monomer having at least two unsaturated functional groups polymerizable, and preferably having a structure consisting of hydrophobic blocks on which are fixed, via the polyfunctional units (c), several more hydrophilic blocks. Preferably, the amphoteric polymers have at least two glass transition temperatures (Tg) of which at least one is greater than 20 ° C and the other is less than 20 ° C.
    [0016] The preferred amphoteric polymers are polymers comprising units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen with an alkyl group; b) with at least one acidic comonomer containing one or more reactive carboxylic groups, and c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituted esters of acrylic and methacrylic acids, and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl. Mention may be made in particular of the polymers sold under the name AMPHOMER by the company National Starch. The nonionic fixing polymers that can be used according to the present invention are chosen, for example, from: polyalkyloxazolines, vinyl acetate homopolymers, vinyl acetate copolymers, such as, for example, copolymers of vinyl acetate, vinyl acetate and acrylic ester, copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and maleic ester, for example, dibutyl maleate, homopolymers and copolymers of acrylic esters, such as, for example, copolymers of alkyl acrylates and of alkyl methacrylates, such as the products offered by the company Rohm & Haas under the names PRIMAL® AC-261 K and EUDRAGIT® NE 30 D , by the company BASF under the name 8845, by HOECHST under the name APPRETAN® N9212, copolymers of acrylonitrile and a nonionic monomer chosen, for example, from butadiene and (meth) acrylates. alkyl, such that the products offered under the name CJ 0601 B by the company ROHM & HAAS, - homopolymers of styrene, - styrene copolymers, for example, copolymers of styrene and (meth) acrylate, such as products MOWILITH® LDM 6911, MOWILITH® DM 611 and MOWILITH® LDM 6070 offered by the company HOECHST, the RHODOPAS® SD 215 and RHODOPAS® DS 910 products offered by the company RHONE POULENC, the copolymers of styrene, of alkyl methacrylate and alkyl acrylate, copolymers of styrene and butadiene, or copolymers of styrene, butadiene and vinylpyridine, polyamides, homopolymers of vinyllactam, such as homopolymers of vinylpyrrolidone, polyvinylcaprolactam marketed under the name Luviskol PLUS by the company BASF; copolymers of vinyllactam, such as a poly (vinylpyrrolidone / vinyllactam) copolymer sold under the trade name Luvitec® VPC 55K65W; BASF, poly (vinylpyrrolidone / vinyl acetate) copolymers such as those sold under the name PVPVA® S630L by the company ISP, Luviskol® VA 73, VA 64, VA 55, VA 37 and VA 28 by the company BASF, and poly (vinylpyrrolidone / vinyl acetate / vinyl propionate) terpolymers, for example those sold under the name Luviskol® VAP 343 by the company BASF, and polyvinyl alcohol.
    [0017] The alkyl groups of the nonionic polymers mentioned above preferably have from 1 to 6 carbon atoms. Preferably, the fixing polymer or polymers used in the aerosol device according to the invention is or are anionic, nonionic or cationic fixing polymers, in particular fixing polymers chosen from acrylic acid copolymers such as acrylic acid terpolymer. ethyl acrylate / N-tert-butylacrylamide, methacrylic acid / ethyl acrylate copolymers, especially in aqueous dispersion, copolymers derived from crotonic acid such as vinyl acetate terpolymers / vinyl tert-butylbenzoate / crotonic acid and terpolymers crotonic acid / vinyl acetate / vinyl neododecanoate, polymers derived from maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters such as monoesterified methyl vinyl ether / maleic anhydride copolymer, anion polyurethanes elastomeric or non-elastomeric polymers, polymers with sulphoisophthalate groups, branched block anionic polymer butyl acrylate / acrylic acid / methacrylic acid; homopolymers of vinyllactam, such as homopolymers of vinylpyrrolidone and polyvinylcaprolactam, copolymers of vinyllactam, such as a poly (vinylpyrrolidone / vinyllactam) copolymer and poly (vinylpyrrolidone / vinyl acetate) copolymers; cationic cellulose derivatives such as copolymers of cellulose or of cellulose derivatives grafted with a water-soluble monomer comprising a quaternary ammonium, and more particularly hydroxyalkyl celluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl-grafted cellulose, in particular with a methacryloyloxyethyl salt; trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyldiallylammonium, and vinylamine / vinylformamide copolymers. More preferably, the fixing polymer or polymers used in the aerosol device according to the invention is or are chosen from branched block anionic polymer, butyl acrylate / acrylic acid / methacrylic acid, homopolymers and copolymers of vinyllactam, such as polyvinylcaprolactam and vinylpyrrolidone / vinyl acetate polymer, vinylamine / vinylformamide copolymer, polyquaternium-4, and mixtures thereof.
    [0018] The fixing polymer (s) is (are) present in an amount of preferably from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, and more preferably preferably from 1 to 8% by weight relative to the total weight of the composition. The surfactants that can be used in the composition according to the invention can be anionic, nonionic, amphoteric or zwitterionic or cationic. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -CO2H, -O2-, -SO3H, -SO3, -OSO3H, -SO3-, -H2PO3, -HPO3-, -PO32, -H2PO2, -HPO2-, -PO2, -POH, -PO-. As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoesters salts of alkyl and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether carboxylic acid salts, alkyl acid salts amidoether carboxylic acids; and the corresponding non-salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 40 carbon atoms, preferably from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.
    [0019] The salts of C 6 -C 24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside-citrates, C 6 -C 24 alkyl polyglycoside-tartrates and polyglycoside-sulphosuccinates. C6-C24 alkyl.
    [0020] When the anionic surfactants are in the form of salts, they may be chosen from alkali metal salts such as sodium or potassium salt and preferably sodium salt, ammonium salts. salts of amines and in particular aminoalcohols or alkaline earth metal salts such as magnesium salt.
    [0021] By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2-amino-2-methyl-1- propanol, 2-amino-2-methyl-1,3-propanediol and tri (hydroxymethyl) amino methane.
    [0022] The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used. In a first variant, the anionic surfactants may be chosen from (C6-C24) alkyl sulphates, (C6-C24) alkyl ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal salts, d ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. Even better, in this variant, the alkyl (C 12 -C 20) sulphates, the (C 12 -C 20) alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, d aminoalcohols, and alkaline earth metals, or a mixture of these compounds. More preferably, sodium lauryl ether sulfate is preferred to 2.2 moles of ethylene oxide.
    [0023] In a second variant, the anionic surfactants may be chosen from surfactants with anionic groups chosen from -C (O) OH, -C (O) O-, -SO31-1, -S (O) 20-, such as alkylsulfonates, alkylamidesulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, acyllactylates, N-acyl glycinates, alkyl and acyl groups of all these compounds having from 6 to 40 carbon atoms, preferably from 6 to 24 carbon atoms. Very particularly, C6-40 acyl glutamates, more preferably C6-24 acyl glutamates, such as, for example, the disodium cocoyl glutamate sold under the trade name PLANTAPON ACG LC by BASF, or C6-40 acyls can be used. ) isethionates, better (C 6-24 acyl) isethionates such as, for example, sodium lauroyl methyl isethionate marketed by INNOSPEC under the trade name ISELUX LQCLR-SB. Examples of nonionic surfactants that can be used in the composition according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178. They are chosen in particular from alcohols, alpha-diols and (C 1 -C 20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 atoms. carbon number, the number of ethylene oxide groups and / or propylene oxide ranging in particular from 2 to 50 and the number of glycerol groups ranging in particular from 2 to 30. Mention may also be made of ethylene oxide condensates and propylene oxide on fatty alcohols, the polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, the polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4, ethoxylated sorbitan fatty acid esters having from 2 to 30 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, C6-C24 alkyls; ) -mono- or polyglycosides, the dice N-C6-C24 alkyl glucamine, amine oxides such as (C10-C14) alkyl amine oxides or N- (C10-C14 acyl) aminopropylmorpholine oxides, or vegetable oils, optionally hydrogenated, and in particular polyethoxylated vegetable oils preferably having from 2 to 60 ethylene oxide units, more preferably from 10 to 50 ethylene oxide units. Particularly preferred nonionic surfactants are chosen from polyethoxylated alcohols, alcohols containing in particular 8 to 18 carbon atoms and the number of ethylene oxide groups ranging in particular from 2 to 50, and optionally hydrogenated vegetable oils, and in particular polyethoxylated vegetable oils preferably having from 2 to 60 ethylene oxide units, more preferably from 10 to 50 ethylene oxide units. The amphoteric or zwitterionic surfactants that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, containing at least one anionic group such as, for example, a carboxylate, sulphonate, sulphate, phosphate or phosphonate, and wherein the aliphatic group or at least one of the aliphatic groups is a linear or branched chain having from 8 to 22 carbon atoms. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulfobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines such as cocoamidopropylbetaine and (C 8 -C 20) alkylamido (C 1 -C 6) alkyl- sulfobetaines. Among the optionally quaternized secondary or tertiary aliphatic amine derivatives that may be used, there may also be mentioned the following products of structures (XII) and (XIII): Ra-CONHCH2CH2-N + (Rb) (R) (CH2C00) -) (XII) in which: Ra represents a C 10 -C 30 alkyl or alkenyl group derived from a Ra-COOH acid, preferably present in hydrolysed coconut oil, a heptyl, nonyl or undecyl group, Rb represents a group beta-hydroxyethyl, and R, is carboxymethyl; Ra-CONHCH2CH2-N (B) (B ') (XIII) wherein: B is -CH2CH2OX', X 'is -CH2-COOH, CH2-COOZ', -CH2CH2-COOH, -CH2CH2-COOZ ', or a hydrogen atom, B 'represents - (CH2) z-Y', with z = 1 or 2, Y 'represents -COOH, -COOZ', the group -CH2-CHOH-SO3H or -CH2-CHOH- SO3Z ', Z' represents an ion derived from an alkali metal or alkaline earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion derived from an organic amine and in particular an aminoalcohol, such as mono-, di- and triethanolamine, mono-, di- or triisopropanolamine, 2-amino-2-methyl-1-propanol 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. Ra, represents a C10-C30 alkyl or alkenyl group of an Ra-COOH acid preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group, in particular a C17 group and its iso form, a unsaturated C17 group.
    [0024] These compounds are also classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacetate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate di sodium, cocoamphodipropionate di sodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, lauroamphodipropionic acid, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. It is also possible to use compounds of formula (XIIIbis): Ra-NH-CH (Y ") - (CH2) .- C (O) -NH- (CH2) .- N (Rd) (Re) (XIIIbis) wherein: Y "represents the group -C (O) OH, -C (O) OZ", -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -803-Z "; Rd and Re, independently of one another, represent a C1-C4 alkyl or hydroxyalkyl group; Z "represents a cationic counterion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra- represents a C10-C30 alkyl or alkenyl group of an acid Ra-C (O) OH preferably present in coconut oil or in hydrolyzed linseed oil, n and n ', independently of each other, denote an integer ranging from 1 to 3. the compounds of formula (XIIIbis), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by the company Chimex under the name Chimexane HB. Preferably, the amphoteric or zwitterionic surfactants are chosen from alkyls (C8-C20) betaines, (C8-C20) alkylamido (C1-C6) alkylbetaines and (C8-C20) alkylamphodiacetates, and mixtures thereof.The amphoteric or zwitterionic surfactants are preferably selected from, alone or in combination with mix, cocoylamlam idopropylbetaine, cocoylbetaine and cocoamphodiacetate. The cationic surfactant or surfactants that can be used in the composition according to the invention comprise, in particular, the optionally polyoxyalkylenated primary, secondary or tertiary fatty amine salts, the quaternary ammonium salts, and mixtures thereof.
    [0025] As quaternary ammonium salts, mention may be made, for example, of: - those corresponding to the following general formula (XIV): ## STR2 ## in which groups R 8 to R 11, which may be identical or different, represent an aliphatic group, linear or branched, having from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R 8 to R 11 comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms The aliphatic groups may comprise heteroatoms such as, in particular, oxygen, nitrogen, sulfur and halogens, and the aliphatic groups may be chosen, for example, from alkyl groups. C1-C30, C1-C30 alkoxy, (C2-C6) polyoxyalkylene, C1-C30 alkylamide, (C12-C22) alkyl (C2-C6) amidoalkyl, (C12-C22) alkyl, and C1-C30 hydroxyalkyl X- is an anion selected from the group of halides, phosphates, acetates, lactates, alkyl (CiC4) sulf ates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylarylsulfonates.
    [0026] Of the quaternary ammonium salts of formula (XIV), tetraalkylammonium chlorides, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides or else palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristylacetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK. the quaternary ammonium salts of imidazoline, for example those of formula (XV) below: embedded image in which XNN R 13 X N CH 2 CH 2 -N (R 15) -CO-R 12 (XV) R 14 R 12 represents an alkenyl or alkyl group comprising from 8 to 30 carbon atoms, for example fatty acid derivatives of tallow, R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group having from 8 to 30 carbon atoms, R14 represents a C1-C4 alkyl group, R15 represents a hydrogen atom, a C1-C4 alkyl group, X- is an anion chosen from the group of halides, phosphates, acetates, lactates, alkyl (Ci-C4) sulphates, alkyls (C1-C4) - or (C1-C4) alkylsulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO. the quaternary di- or triammonium salts, in particular of the following formula (XVI): R 17 R 19 R 16 -N- (Cl-12) N-R 21 R 18 R 20 (XVI) in which R 16 denotes an alkyl group comprising about 16 at 30 carbon atoms optionally hydroxylated and / or interrupted by one or more oxygen atoms, R 17 is chosen from hydrogen or an alkyl group containing from 1 to 4 carbon atoms or a - (CH 2) 3 N + group ( R 16 a) (R 17 a) (R 18 a) R 16a, Rua, R 18a, R 18, R 19, R 20 and R 21, which may be identical or different, are chosen from hydrogen or an alkyl group containing from 1 to 4 carbon atoms, and X is an anion chosen from the group of halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylsulphonates, in particular methylsulphate and ethylsulphate.
    [0027] Such compounds are, for example, the Finquat CT-P proposed by Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75). quaternary ammonium salts containing one or more ester functional groups, such as, for example, those of the following formula (XVII): ## STR2 ## Wherein R 22 is selected from C 1 -C 6 alkyl groups and C 1 -C 6 hydroxyalkyl or dihydroxyalkyl groups, 2+ 2X-R 23 is selected from: o - the group R2 C- - the linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon-based R 27 groups, - the hydrogen atom, R 25 is chosen from: o - the R 2c group - - the R 29 hydrocarbon groups in Ci-C6, linear or branched, saturated or unsaturated, - the hydrogen atom, R24, R26 and R28, identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon groups; , s and t, which are identical or different, are integers from 2 to 6, r 1 and t 1, which are identical or different, are equal to 0 or 1, r 2 + r 1 = 2 r and t 1 + t 2 = 2 t, y is an integer are from 1 at 10, x and z, which are identical or different, are integers ranging from 0 to 10, X- is a simple or complex anion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29. The alkyl groups R22 may be linear or branched and more particularly linear. Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10.
    [0028] When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms. When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C 1 -C 21 hydrocarbon-based groups, and more particularly from linear or branched, saturated or saturated C 11 -C 21 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, which are identical or different, are equal to 0 or 1. Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are equal to 2 or 3, and even more particularly are equal to 2 .
    [0029] The anion X- is preferably a halide, preferably chloride, bromide or iodide, a (C1-C4) alkyl sulfate, a (C1-C4) alkyl or (C1-C4) alkyl aryl sulfonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. The anion X- is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (XVII) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, - r, s and t are equal to 2, - R23 is chosen from: 0II -the R2c group - - methyl, ethyl or C14-C22 hydrocarbon groups, - the hydrogen atom, - R25 is chosen among: - the group R2 - the hydrogen atom, - R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl groups. Advantageously, the hydrocarbon groups are linear.
    [0030] Examples of the compounds of formula (XVII) that may be mentioned include salts, in particular diacyloxyethyldimethylammonium chloride, diacyloxyethylhydroxyethylmethylammonium chloride, monoacyloxyethyldihydroxyethylmethylammonium chloride, triacyloxyethylmethylammonium chloride, monoacyloxyethylhydroxyethyldimethylammonium chloride, and mixtures thereof. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different.
    [0031] These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent, such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulfate. ethyl, methyl methanesulfonate, methyl para-toluenesulfonate, chlorohydrin glycol or glycerol. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.
    [0032] The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. By way of examples of such compounds, mention may be made of distearoylethylhydroxyethylmethylammonium or dipalmitoylethylhydroxyethylmethylammonium salts, and in particular the methosulphates. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A4137180.
    [0033] It is also possible to use behenoylhydroxypropyltrimethylammonium chloride, for example, proposed by the company KAO under the name Quartamin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions.
    [0034] Among the cationic surfactants, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethyl-hydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride and dipalmitoylethylhydroxyethylammonium methosulfate. , and their mixtures. In a particular embodiment of the invention, the hair composition comprises one or more surfactants chosen from (C 6 -C 24) alkyl sulphates, C 6 -C 24 alkyl ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal salts, ammonium, aminoalcohols, and alkaline earth metals; polyethoxylated C 8-18 alcohols, the number of ethylene oxide groups ranging from 2 to 50, optionally hydrogenated vegetable oils, and in particular polyethoxylated vegetable oils preferably having from 2 to 60 ethylene oxide units, more preferably from 10 to 50 ethylene oxide units; (C8-C20) alkyl betaines, (C8-C20) alkylamido (C1-C6) alkyl betaines and (C8-C20) alkyl amphodiacetates; and the quaternary ammonium salts of formula (XIV), especially cetyltrimethylammonium salts; and their mixtures. Preferably, the composition according to the invention contains one or more nonionic surfactant (s).
    [0035] The composition according to the invention preferably has a total content of surfactant (s) of less than or equal to 10% by weight, better still less than 8% by weight, better still less than 7.5% by weight relative to the total weight of the composition. More particularly, said total content of surfactant (s) can range from 0.05 to 10% by weight, better still from 0.1 to 8% by weight, and still more preferably from 0.2 to 5% by weight relative to total weight of the composition. Preferably, the weight ratio of the total amount of polymer (s) fixing (s) on the total amount of surfactant (s) is greater than or equal to 0.5, better from 0.5 to 15, and better still goes from 0.6 to 8. The composition according to the invention also contains water. Preferably, it contains more than 5% by weight of water, still more preferably 20 to 95% by weight, and more preferably 50 to 90% by weight of water relative to the total weight of the composition. Examples of propellants useful in the aerosol device of the present invention are liquefied gases such as dimethyl ether, 1,1-difluoroethane, or C 3 -C 5 alkanes such as propane, isopropane, n-butane isobutane, pentane, or compressed gases such as air, nitrogen, carbon dioxide, and mixtures thereof. Preferentially, there may be mentioned dimethyl ether, 1,1-difluoroethane, C 3 -C 5 alkanes such as propane, n-butane and isobutane, and mixtures thereof. The propellant (s) is (are) present in an amount of less than 20% by weight, preferably less than 15% by weight, more preferably 1 to 14% by weight, and more preferably preferably from 3 to 12% by weight relative to the total weight of the composition.
    [0036] In one embodiment, the composition according to the invention further comprises one or more thickening polymers. As examples of thickening polymer, there may be mentioned acrylic polymers, polysaccharides and associative polymers. Preferably, the thickening polymer is chosen from polysaccharides, in particular from cellulosic polymers or scleroglucan gums. When present (s), the amount of the OR thickening polymer (s) is preferably from 0.05 to 10% by weight, more preferably from 0.05 to 5% by weight, and even more preferably from 0.08 to 2% by weight relative to the total weight of the composition. The composition contained in the aerosol device according to the invention may also contain one or more additives chosen from silicone derivatives in soluble, dispersed, micro-dispersed forms, solvents such as ethanol, clays such as bentone and hectorite, silica, plasticizers, anti-caking agents, protective filters, acids, bases, pearlescent agents, glitter and perfumes, permanent or temporary dyes, and treating active ingredients. These additives may be present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.
    [0037] Those skilled in the art will take care to choose these optional additives and their amounts so that they do not adversely affect the properties of the compositions of the present invention. The compositions in accordance with the invention are packaged in an aerosol device that is usual in cosmetics.
    [0038] The aerosol device used to condition the composition of the invention may consist of an external aerosol can which contains both the propellant (s) and the other ingredients of the composition, in a single compartment. Preferably, said device is equipped with a valve and also comprises a push button which is provided with a diffuser. According to another variant, the aerosol device may be in two compartments, constituted by an external aerosol can comprising an internal pouch hermetically sealed to a valve. The various ingredients of the composition are introduced into the inner bag and a compressed gas is introduced between the bag and the can at a pressure sufficient to release the product. According to this variant, the device is also equipped with a valve and comprises a push-button which is provided with a diffuser. The sprayed compositions are preferably in the form of a foam. The present invention also relates to a method of treatment, and in particular of shaping the hair and / or maintaining the hairstyle, comprising the use of a composition as described above. In particular, the method of shaping and / or maintaining the hairstyle comprises a step of applying to the hair, dry or wet, a composition as defined previously sprayed from an aerosol device according to the invention. invention, to rinse or not after a possible exposure time or after any drying. Preferably, the composition according to the invention is not rinsed. The composition according to the invention can thus be used on dry or wet hair. Preferably, the composition is applied to clean hair. According to a particular embodiment of the invention, the application of the composition may be followed by drying at room temperature or at a temperature above 40 ° C.
    [0039] Drying can be carried out immediately after application or after a laying time ranging from 1 minute to 30 minutes. The present invention also relates to the use of the above-defined composition sprayed from the aerosol device according to the invention, for shaping the hair and / or maintaining the hairstyle, and in particular for imparting volume to the hair. hairdressing. The following examples serve to illustrate the invention.
    [0040] EXAMPLES In the following examples, all the amounts are indicated as weight percent of product in active materials relative to the total weight of the composition.
    [0041] Example 1 The following compositions according to the invention were prepared from the compounds indicated in the table below.
    [0042] Composition ABCDEF Calcium carbonate ") 5 2 1 1 0.8 3 Polyvinylcaprolactam (2) 1,2 2 - - - - Copolymer - - - 6 - - vinylpyrrolidone / vinyl acetate") Polyquaternium-4 (4) - - 2 - - - Copolymer - - - - 7,7 - vinylamine / vinylformamide (5) Copolymer AMP-acrylates / - - - - - 7.5 allyl methacrylate (6) Hydroxyethylcellulose (7) - 0,1 - - 0, Scleroglucan gum (8) 0.4 - - 0.3 - 0.22 Hydrogenated and polyoxyethylenated castor oil (PEG-40) 0.8 0.5 0.7 0.6 0.7 0.6 Chloride - - 0,05 0,06 0,08 - cetyltrimethylammonium Laureth-4 1 - 0,5 - 0,2 0,4 Cocamidopropyl betaine - - - 0,2 - sodium lauryl sulphate - 0,35 - - - 0, 07 Propylene glycol - 3 - - 2 - Fragrance 0.3 0.3 0.3 0.3 0.3 0.3 Preservative 0.3 0.3 0.3 0.3 0.3 0.3 Ethanol - - - 3 - - Isobutane / Butane / Propane (9) 4,5,5 4,5 5 6 Dimethyl ether - - - 1,5 - 1,1-difluoroethane (10) - 1,5 - - - Water qs 100 100 100 100 100 100 (1): sold under the trade name OMYACARE S 60-AV by the company OMY A, (2): sold under the trade name LUVISKOL PLUS by the company BASF, (3): sold under the trade name LUVISKOL VA 64 W by the company BASF, (4): sold under the trade name CELQUAT LOR by the company Akzo Nobel, (5): sold under the trade name LUVIQUAT 9030 by the company BASF, (6): sold under the trade name FIXATE G-100L PR POLYMER by the company Lubrizol, (7): sold under the trade name NATROSOL 250 HHR PC by the company Ashland, (8): sold under the trade name AMIGEL by the company Alban Muller, (9): sold under the trade name PROPEL 45 by the company Repsol, (10): sold under the trade name DYMEL 152 A by the company Dupont.
    [0043] Each composition was then introduced into an aerosol device which comprises a 210 ml aluminum can equipped with a foam propelling device comprising a valve, in particular an accuracy valve P14180, and a foam diffuser, in particular a precision diffuser. DMPR190, the valve and the diffuser being sold by Valve Précision. Foam compositions were applied to a hair. After application of the foam, one notes a contribution of volume, texturization and body to the fibers while keeping a natural aspect of the hair without helmet effect.
    [0044] Example 2 A composition of a commercial product (composition H) was compared with a composition according to the invention (composition G).
    [0045] Composition GH (Invention) (Comparative) Calcium carbonate ") 5.23 - Polyquaternium-4 (2) 1.43 1.41 Scleroglucan gum (3) 0.29 - Hydrogenated castor oil and 0.86 0.85 polyoxyethylenated (PEG-40) Cetyltrimethylammonium chloride 0.05 0.05 Laureth-4 0.38 0.38 Perfume 0.29 0.19 Phenoxyethanol 0.67 0.47 Preservative qs qs Propylene glycol 2.38 2.35 Isobutane / Butane / Propane (4) 5 6 Water qs 100 100 (1): Sold under the trade name OMYACARE S 60-AV by the company OMYA, (2): sold under the trade name CELQUAT LOR by the company Akzo Nobel, ( 3): sold under the trade name AMIGEL by Alban Muller, (4): sold under the trade name PROPEL 45 by the company Repsol.
    [0046] Each composition was then introduced into an aerosol device which comprises a 210 ml aluminum can equipped with a foam propelling device comprising a valve, in particular an accuracy valve P14180, and a foam diffuser, in particular a precision diffuser. DMPR190, the valve and the diffuser being sold by Valve Précision. 2 g were applied. each of the foams on the damp hair by half-head. This application was done on 6 heads for each of the compositions.
    [0047] The qualities of use in the application and the cosmetic properties conferred on the hair after blow drying were then evaluated. It was found that: - at the application, more texturization is obtained with the composition G according to the invention, and - after blow-drying, the hair treated with the composition G according to the invention have more texturization and more mass.
    权利要求:
    Claims (18)
    [0001]
    REVENDICATIONS1. An aerosol device which contains a composition comprising: (i) one or more calcium salts insoluble in water, (ii) one or more fixing polymers, (iii) one or more surfactants, (iv) water, and v) less than 20% by weight, relative to the total weight of the composition, of one or more propellants.
    [0002]
    2. aerosol device according to claim 1, characterized in that the calcium salt insoluble in water is calcium carbonate.
    [0003]
    3. aerosol device according to claim 1 or 2, characterized in that the water insoluble calcium salt is in the form of powder comprising particles which have an average diameter of 2 to 50 i.tm.
    [0004]
    4. aerosol device according to any one of the preceding claims, characterized in that the salt (s) of calcium insoluble in water is or are present in an amount of 0.1 at 15% by weight, preferably from 0.5 to 10% by weight, better still from 0.7 to 6% by weight relative to the total weight of the composition.
    [0005]
    5. aerosol device according to any one of the preceding claims, characterized in that the (s) polymer (s) fixing (s) is (are) selected from the anionic fixing polymers, nonionic and cationic.
    [0006]
    6. aerosol device according to any one of the preceding claims, characterized in that the (s) polymer (s) fixing (s) is (are) selected from the anionic polymer branched chain butyl acrylate / acrylic acid / acid methacrylic acid homopolymers and copolymers of vinyllactam, such as polyvinylcaprolactam and vinylpyrrolidone / acetate divinyl polymer, vinylamine / vinylformamide copolymer, polyquaternium4, and mixtures thereof.
    [0007]
    Aerosol device according to any one of the preceding claims, characterized in that the fixing polymer (s) is (are) present in an amount ranging from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, better still from 1 to 8% by weight relative to the total weight of the composition.
    [0008]
    8. aerosol device according to any one of the preceding claims, characterized in that the (s) surfactant (s) is or are selected from anionic surfactants, cationic, nonionic, amphoteric and zwitterionic.
    [0009]
    9. aerosol device according to any one of the preceding claims, characterized in that the (s) surfactant (s) is or are selected from alkyl (C6-C24) sulfates, alkyl (C6-C24) ether sulfates comprising 2 50 ethylene oxide units, especially in the form of alkali metal salts, ammonium, aminoalcohols, and alkaline earth metals; polyethoxylated C 8-18 alcohols, the number of ethylene oxide groups ranging in particular from 2 to 50, optionally hydrogenated vegetable oils, and in particular polyethoxylated vegetable oils preferably having from 2 to 60 ethylene oxide units; preferably from 10 to 50 ethylene oxide units; (C8-C20) alkyl betaines, (C8-C20) alkylamido (C1-C6) alkyl betaines and (C8-C20) alkyl amphodiacetates; and cetyltrimethylammonium salts; and their mixtures.
    [0010]
    10. aerosol device according to any one of the preceding claims, characterized in that the (s) surfactant (s) is or are present (s) in an amount ranging from 0.05 to 10% by weight, preferably 0 , 1 to 8% by weight, better still from 0.2 to 5% by weight relative to the total weight of the composition.
    [0011]
    Aerosol device according to one of the preceding claims, characterized in that the propellant (s) is (are) chosen from dimethyl ether, 1,1-difluoroethane and C3-5 alkanes, and their mixtures.
    [0012]
    Aerosol device according to one of the preceding claims, characterized in that the propellant (s) is present in an amount of less than 15% by weight, preferably 1 to 14%, better from 3 to 12%, relative to the total weight of the composition.
    [0013]
    Aerosol device according to one of the preceding claims, characterized in that the composition contains more than 5% by weight of water, preferably 20 to 95% by weight, more preferably 50 to 90% by weight relative to to the total weight of the composition.
    [0014]
    14. aerosol device according to any one of the preceding claims, characterized in that the composition comprises one or more thickening polymers, preferably in an amount ranging from 0.05 to 10% by weight, more preferably from 0.05 to 5% by weight, better still from 0.08 to 2% by weight relative to the total weight of the composition.
    [0015]
    15. aerosol device according to claim 14, characterized in that the thickening polymer is selected from polysaccharides, preferably from cellulosic polymers and scleroglucan gums.
    [0016]
    16. aerosol device according to any one of the preceding claims, characterized in that the composition comprises one or more additives selected from silicone derivatives in soluble, dispersed, micro-dispersed, solvents such as ethanol, clays such as bentone or hectorite, silica, plasticizers, anti-caking agents, protective filters, acids, bases, pearlescent agents, glitter and perfumes, permanent or temporary dyes, and treating active ingredients.
    [0017]
    17. A method of shaping the hair and / or maintaining the hairstyle, comprising a step of applying to the hair, dry or wet, a composition sprayed from an aerosol device according to any one of the 1 to 16, to rinse or not after a possible exposure time or after any drying.
    [0018]
    18. Use of a composition sprayed from an aerosol device according to any one of claims 1 to 16, for shaping the hair and / or maintaining the hairstyle.
    类似技术:
    公开号 | 公开日 | 专利标题
    FR3022770A1|2016-01-01|AEROSOL DEVICE BASED ON CALCIUM SALT, FIXING POLYMER, SURFACTANT AND WATER
    FR2990131A1|2013-11-08|AEROSOL DEVICE BASED ON CALCIUM SALT AND FIXING POLYMER
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    CA2490699A1|2005-06-19|Hairdressing compound comprising, in a mostly aqueous medium, an elastic cationic polyurethane, processes for applying it and its uses
    FR2898050A1|2007-09-07|Cosmetic composition, useful for cosmetic hair treatment to produce capillary and for the hairstyle structuring and/or maintenance, comprises a fatty acid ester and a |acrylate/|acrylate hydroxyester copolymer
    FR3009679A1|2015-02-20|COMPOSITION COMPRISING A SILANE AND A SPECIAL THICKENING POLYMER
    FR3002143A1|2014-08-22|COSMETIC COMPOSITION COMPRISING A VINYLFORMAMIDE / VINYLFORMAMINE COPOLYMER, A CELLULOSIC THICKENING POLYMER AND AN AMPHOTERE OR ZWITTERIONIC SURFACTANT
    FR2984136A1|2013-06-21|COSMETIC COMPOSITION COMPRISING AN ANIONIC OR NON-IONIC ASSOCIATIVE POLYMER, A FIXING POLYMER AND A PARTICULAR SURFACTANT AND USE IN STAPLING
    WO2007099268A2|2007-09-07|Cosmetic composition comprising a fatty acid ester and an acrylate or methacrylate and acrylate or methacrylate hydroxyester copolymer, and the use thereof as a hair care product
    EP1892014B1|2011-09-14|Cosmetic composition containing at least one lambda carrageenan type polysaccharide in aerosol form; cosmetic treatment method of keratin fibres and use of the composition
    FR3045361A1|2017-06-23|COMPOSITION COMPRISING A VINYLFORMAMIDE / VINYLAMINE COPOLYMER, A FIXING POLYMER AND A PARTICULAR ASSOCIATION OF SURFACTANT AGENTS
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    FR3068886B1|2019-08-30|AQUEOUS COSMETIC COMPOSITION COMPRISING A PYRIDINE-DICARBOXYLIC ACID DERIVATIVE AND A HYDROXYSTILBENE
    FR2795954A1|2001-01-12|Cosmetic composition for treatment of keratin matter, especially hair, contains at least one cationic fructane and at least one hair-treatment polymer
    FR3070127B1|2019-09-13|AQUEOUS COSMETIC COMPOSITION COMPRISING A CHEMICAL OXIDIZING AGENT, A FIXING POLYMER AND MONTMORILLONITE
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    FR3006893A1|2014-12-19|COSMETIC COMPOSITION COMPRISING A MINERAL WAX, A FATTY ACID, A MINERAL OIL, A PARTICULAR NON-IONIC SURFACTANT, A PARTICULATE SOLID FATTY BODY AND A FIXING POLYMER
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    FR2994653A1|2014-02-28|Composition in compressed form, useful for bleaching keratin fibers e.g. human hair, comprises persulfate including e.g. sodium persulfate, and anionic and nonionic fixing polymer
    FR3104954A1|2021-06-25|Process for the cosmetic treatment of keratin fibers using a rare earth and a particular polymer
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    EP2651372A2|2013-10-23|Aerosol device having two compartments including an alcoholic or hydroalcoholic hairstyling composition, and hairstyling method
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    同族专利:
    公开号 | 公开日
    EP3160436A1|2017-05-03|
    EP3160436B1|2018-09-26|
    WO2016001190A1|2016-01-07|
    US20180200161A1|2018-07-19|
    FR3022770B1|2016-07-29|
    US11154466B2|2021-10-26|
    ES2693541T3|2018-12-12|
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    法律状态:
    2015-06-08| PLFP| Fee payment|Year of fee payment: 2 |
    2016-01-01| PLSC| Publication of the preliminary search report|Effective date: 20160101 |
    2016-05-16| PLFP| Fee payment|Year of fee payment: 3 |
    2017-05-11| PLFP| Fee payment|Year of fee payment: 4 |
    2018-05-11| PLFP| Fee payment|Year of fee payment: 5 |
    2019-05-10| PLFP| Fee payment|Year of fee payment: 6 |
    2021-03-12| ST| Notification of lapse|Effective date: 20210205 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1456128A|FR3022770B1|2014-06-30|2014-06-30|AEROSOL DEVICE BASED ON CALCIUM SALT, FIXING POLYMER, SURFACTANT AND WATER|FR1456128A| FR3022770B1|2014-06-30|2014-06-30|AEROSOL DEVICE BASED ON CALCIUM SALT, FIXING POLYMER, SURFACTANT AND WATER|
    US15/322,771| US11154466B2|2014-06-30|2015-06-30|Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water|
    PCT/EP2015/064780| WO2016001190A1|2014-06-30|2015-06-30|Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water|
    ES15735655.1T| ES2693541T3|2014-06-30|2015-06-30|Aerosol device based on a calcium salt, a fixative polymer, a surfactant and water|
    EP15735655.1A| EP3160436B1|2014-06-30|2015-06-30|Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water|
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